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Presents electron transfer & double-layer theories in an understandable manner while keeping mathematics to a minimum. Revised & expanded, this edition features a number of new sections which deal with electrochemical materials science, photoelectrochemistry, stochastic processes, novel aspects of ion transfer across biological membranes, biosensors & more.
Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)
This introduction to the principles and application of electrochemistry is presented in a manner designed for undergraduates in chemistry and related fields. The author covers the essential aspects of the subject and points the way to further study, his concern being with the overall shape of electrochemistry, its coherence and its wider application. This edition differs from its predecessors in having principles and applications separated, and greater prominence is given to areas such as electrochemical sensors and electroanalytical techniques, of which a number of modern methods were not included in previous editions. A range of numerical problems and outline solutions is provided for each chapter to cover most situations that a student might encounter.
Third Edition covers the latest advances in methodologies, sensors,detectors, and mIcrochips The greatly expanded Third Edition of this internationallyrespected text continues to provide readers with a completepanorama of electroanalytical techniques and devices, offering abalancebetween voltammetric and potentiometric techniques.Emphasizing electroanalysis rather than physical electrochemistry,readers gain a deep understanding of the fundamentals ofelectrodereactions and electrochemical methods. Moreover, readerslearn to apply their newfoundknowledge and skills to solvereal-world analytical problems. The text consists of six expertly crafted chapters: * Chapter 1 introduces fundamental aspects of electrode reactionsand the structure of the interfacial region * Chapter 2 studies electrode reactions and high-resolution surfacecharacterization, using techniques ranging from cyclic voltammetryto scanning probe microscopies * Chapter 3 features an overview of modern finite-currentcontrolled potential techniques * Chapter 4 presents electrochemical instrumentation and electrodematerials, including modified electrodes andultramicroelectrodes * Chapter 5 details the principles of potentiometric measurementsand various classes of ion selective electrodes * Chapter 6 explores the growing field of chemical sensors,including biosensors, gas sensors, microchip devices, and sensorarrays Among the new topics covered, readers discover DNA biosensors,impedance spectroscopy, detection of capillary electrophoresis,diamond electrodes, carbon-nanotube and nanoparticle-based arraysand devices, large-amplitude AC voltammetry, solid-stateion-selective electrodes, ion selective electrodes for traceanalysis, and lab-on-a-chip devices. New figures, worked examples,and end-of-chapter questions have also been added to thisedition. Given the rapid pace of discovery and growth of new applications inthe field, this text is essential for an up-to-date presentation ofthe latest advances in methodologies, sensors, detectors, andmicrochips. It is recommended for graduate-level courses inelectroanalytical chemistry and as a supplement for upper-levelundergraduate courses in instrumental analysis. The text also meetsthe reference needs for any industry, government, or academiclaboratory engaged in electroanalysis and biosensors.
A Comprehensive Reference for Electrochemical Engineering Theory and Application From chemical and electronics manufacturing, to hybrid vehicles, energy storage, and beyond, electrochemical engineering touches many industries—any many lives—every day. As energy conservation becomes of central importance, so too does the science that helps us reduce consumption, reduce waste, and lessen our impact on the planet. Electrochemical Engineering provides a reference for scientists and engineers working with electrochemical processes, and a rigorous, thorough text for graduate students and upper-division undergraduates. Merging theoretical concepts with widespread application, this book is designed to provide critical knowledge in a real-world context. Beginning with the fundamental principles underpinning the field, the discussion moves into industrial and manufacturing processes that blend central ideas to provide an advanced understanding while explaining observable results. Fully-worked illustrations simplify complex processes, and end-of chapter questions help reinforce essential knowledge. With in-depth coverage of both the practical and theoretical, this book is both a thorough introduction to and a useful reference for the field. Rigorous in depth, yet grounded in relevance, Electrochemical Engineering: Introduces basic principles from the standpoint of practical application Explores the kinetics of electrochemical reactions with discussion on thermodynamics, reaction fundamentals, and transport Covers battery and fuel cell characteristics, mechanisms, and system design Delves into the design and mechanics of hybrid and electric vehicles, including regenerative braking, start-stop hybrids, and fuel cell systems Examines electrodeposition, redox-flow batteries, electrolysis, regenerative fuel cells, semiconductors, and other applications of electrochemical engineering principles Overlapping chemical engineering, chemistry, material science, mechanical engineering, and electrical engineering, electrochemical engineering covers a diverse array of phenomena explained by some of the important scientific discoveries of our time. Electrochemical Engineering provides the critical understanding required to work effectively with these processes as they become increasingly central to global sustainability.
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This book describes the origin, use, and limitations of electrochemical phase diagrams, testing schemes for active, passive, and localized corrosion, the development and electrochemical characterization of passivity, and methods in process alteration, failure prediction, and materials selection. It offers useful guidelines for assessing the efficacy of corrosion inhibitors and coatings for metals and alloys, developing effective corrosion prediction models, calculating the corrosion rates of various materials, determining the resistance of alloys to pitting and crevice corrosion, and considering current and potential distribution effects on corrosion.

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